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  1. Free, publicly-accessible full text available October 1, 2024
  2. Abstract

    Since 2013, extreme floods within the Santee River basin (North/South Carolina, USA) caused $1.5B in damage. The instrumental period, however, is too short to determine if recent extreme events are anomalous within a long‐term context. Here, we present reconstructions of storm‐, base‐, and total streamflow for the Santee River using a multi‐species tree‐ring network calibrated to flow data during the period 1923–2018. Tree‐ring data explained higher variance (r = 0.59;p < 0.01; 900–2018) of instrumental baseflow than total streamflow (r = 0.41;p < 0.01; 1500–2018) or stormflow (r = 0.26;p < 0.05; 1690–2018). Our reconstruction reveals a long‐term increase in baseflow over the past millennium. The North Atlantic subtropical high regulates baseflow in the Santee River (r = 0.45;p < 0.01). Recent high levels of baseflow may be connected to the position of the subtropical high, increasing the likelihood of flooding.

     
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  3. Abstract

    Cyclostratigraphy and astrochronology are now at the forefront of geologic timekeeping. While this technique heavily relies on the accuracy of astronomical calculations, solar system chaos limits how far back astronomical calculations can be performed with confidence. High‐resolution paleoclimate records with Milankovitch imprints now allow reversing the traditional cyclostratigraphic approach: Middle Eocene drift sediments from Newfoundland Ridge are well‐suited for this purpose, due to high sedimentation rates and distinct lithological cycles. Per contra, the stratigraphies of Integrated Ocean Drilling Program Sites U1408–U1410 are highly complex with several hiatuses. Here, we built a two‐site composite and constructed a conservative age‐depth model to provide a reliable chronology for this rhythmic, highly resolved (<1 kyr) sedimentary archive. Astronomical components (g‐terms and precession constant) are extracted from proxy time‐series using two different techniques, producing consistent results. We find astronomical frequencies up to 4% lower than reported in astronomical solution La04. This solution, however, was smoothed over 20‐Myr intervals, and our results therefore provide constraints on g‐term variability on shorter, million‐year timescales. We also report first evidence that theg4g3“grand eccentricity cycle” may have had a 1.2‐Myr period around 41 Ma, contrary to its 2.4‐Myr periodicity today. Our median precession constant estimate (51.28 ± 0.56″/year) confirms earlier indicators of a relatively low rate of tidal dissipation in the Paleogene. Newfoundland Ridge drift sediments thus enable a reliable reconstruction of astronomical components at the limit of validity of current astronomical calculations, extracted from geologic data, providing a new target for the next generation of astronomical calculations.

     
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  4. The longleaf pine ( Pinus palustris Mill.) and related ecosystem is an icon of the southeastern United States (US). Once covering an estimated 37 million ha from Texas to Florida to Virginia, the near-extirpation of, and subsequent restoration efforts for, the species has been well-documented over the past ca. 100 years. Although longleaf pine is one of the longest-lived tree species in the southeastern US—with documented ages of over 400 years—its use has not been reviewed in the field of dendrochronology. In this paper, we review the utility of longleaf pine tree-ring data within the applications of four primary, topical research areas: climatology and paleoclimate reconstruction, fire history, ecology, and archeology/cultural studies. Further, we highlight knowledge gaps in these topical areas, for which we introduce the Longleaf Tree-Ring Network (LTRN). The overarching purpose of the LTRN is to coalesce partners and data to expand the scientific use of longleaf pine tree-ring data across the southeastern US. As a first example of LTRN analytics, we show that the development of seasonwood chronologies (earlywood width, latewood width, and total width) enhances the utility of longleaf pine tree-ring data, indicating the value of these seasonwood metrics for future studies. We find that at 21 sites distributed across the species’ range, latewood width chronologies outperform both their earlywood and total width counterparts in mean correlation coefficient (RBAR = 0.55, 0.46, 0.52, respectively). Strategic plans for increasing the utility of longleaf pine dendrochronology in the southeastern US include [1] saving remnant material ( e.g., stumps, logs, and building construction timbers) from decay, extraction, and fire consumption to help extend tree-ring records, and [2] developing new chronologies in LTRN spatial gaps to facilitate broad-scale analyses of longleaf pine ecosystems within the context of the topical groups presented.

     
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  5. Abstract

    Aside from band gap reduction, little is understood about the effect of the tin‐for‐lead substitution on the fundamental optical and optoelectronic properties of metal halide perovskites (MHPs), especially when transitioning from 3D to lower dimensional structures. Herein, we take advantage of the spectroscopic isolation of excitons in 2D MHPs to study the intrinsic differences between lead and tin MHPs. The exciton's spectral fine structure indicates a larger polaron binding energy in tin MHPs. Additionally, the electroabsorption responses of the 2D MHPs demonstrates that tin MHPs have exciton binding energies 1.5–2× lower than that of their lead counterparts. Despite the lower binding energy, the excitons in tin MHPs are more Frenkel‐like with small radii, small polarizabilities, and large dipole moments. These results are interpreted as consequences of small polaron formation and disorder‐induced dipole moments. This work highlights the wide range of intrinsic differences between lead and tin MHPs as well as the complexity of excited states in these systems.

     
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